Proceedings of the 10th Asian Conference on Solid State Ionics : Advanced Materials for Emerging Technologies - Kandy, Sri Lanka, 12-16 June 2006.

By: Chowdari, B. V. RContributor(s): Careem, M. A | Dissanayake, M. A. K. LMaterial type: TextTextPublisher: Singapore : World Scientific Publishing Co Pte Ltd, 2006Copyright date: ©2006Description: 1 online resource (920 pages)Content type: text Media type: computer Carrier type: online resourceISBN: 9789812773104Subject(s): Ions -- Congresses | Semiconductors -- Congresses | Solid state electronics -- CongressesGenre/Form: Electronic books.Additional physical formats: Print version:: Proceedings of the 10th Asian Conference on Solid State Ionics : Advanced Materials for Emerging Technologies - Kandy, Sri Lanka, 12-16 June 2006DDC classification: 621.3815 LOC classification: TK7871.85.A8 2006Online resources: Click to View
Contents:
Intro -- Contents -- Preface -- Keynote Lecture -- Challenges and Opportunities of Solid State Ionic Devices -- Part I: Ionically Conducting Inorganic Solids -- Invited Papers -- Multinuclear NMR Studies of Mass Transport of Phosphoric Acid in Water -- Crystalline, Glassy and Polymeric Electrolytes: Similarities and Differences in Ionic Transport Mechanisms -- 30 Years of NMR/NQR Experiments in Solid Electrolytes -- Analysis of Conductivity and NMR Measurements in Li3xLa2/3-xTiO3 Fast Li+ Ionic Conductor: Evidence for Correlated Li+ Motion -- Transport Pathways for Ions in Disordered Solids from Bond Valence Mismatch Landscapes -- The Proton Conductivity in Condensed Phases of Water: Implications on Linear and Ball Lightning -- Contributed Papers -- Proton Transport in Nanocrystalline Bioceramic Materials: An Investigative Study of Synthetic Bone with that of Natural Bone -- Synthesis and Properties of the Nanostructured Fast Ionic Conductor Li0.3La0.56TiO3 -- Hydrogen Production: Ceramic Materials for High Temperature Water Electrolysis -- Influence of the Sintering Temperature on pH Sensor Ability of Li3xLa2/3-xTiO3. Relationship between Potentiometric and Impedance Spectroscopy Measurements -- Microstructure Chracterization and Ionic Conductivity of Nano-Sized CeO2-Sm2O3 (x = 0.05 - 0.2) System Prepared by Combustion Route -- Red Soil in Northern Sri Lanka is a Natural Magnetic Ceramic -- Neutron Scattering of LiNiO2 -- Preparation and Properties of LiFePO4 Nanorods -- Structural and Electrochemical Properties of Monoclinic and Othorhombic MoO3 Phases -- Preparation of Zircon (ZrSiO4) Ceramics via Solid State Sintering of ZrO2 and SiO2 and the Effect of Dopants on the Zircon Yield -- Preparation and Properties of Vanadium Doped ZnTe Cermet Thin Films -- Dynamical Properties and Electronic Structure of Lithium-ion Conductor.
Cuprous Ion Conducting Montmorillonite- Polypyrrole Nanocomposites -- Frequency Dependence of Conductivity Studies on a Newly Synthesized Superionic Solid Solution/Mixed System: [0.75AgI: 0.25AgCl] -- Diffuse X-ray and Neutron Scattering from Powder PbS -- Electron Affinity and Work Function of Pyrolytic MnO2 Thin Films Prepared from Mn(C2H3O2)2.4H2O -- Crystal Structure and Heat Capacity of Ba3Ca1.18Nb1.82O8.73 -- XPS and Impedance Investigations on Amorphous Vanadium Oxide Thin Films -- Sintering and Mixed Electronic-Ionic Conducting Properties of La1.9Sr0.1NiO4+8 Derived from a Polyaminocarboxylate Complex Precursor -- Preparation and Characteristics of Ball Milled MgH2 + M (M = Fe, FeF3 and VF3) Nanocomposites for Hydrogen Storage -- Structural Studies of Oxysulfide Glasses by X-Ray Diffraction and Molecular Dynamics Simulation -- Synthesis, Sintering and Oxygen Ionic Conducting Properties of Bi2V0.9Cu0.1O5.5-δ -- Synthesis and Transport Characteristics of PbI2-Ag2O-Cr2O3 Superionic System -- Electronic Conductivity of La0.8Sr0.2Ga0.8Mg0.2-xCoxO3-δ Electrolytes (II) -- Part II: Electrode Materials -- Invited Papers -- Cathodic Properties of Al-Doped LiCoO2 Prepared by Molten Salt Method for Li-Ion Batteries -- Layered Ion-Electron Conducting Materials -- LiNi0.80Co0.20O2 Cathode Thin-film Prepared by RF Sputtering for All-Solid-State Rechargeable Microbatteries -- Contributed Papers -- Nanocomposite Cathode for SOFCs Prepared by Electrostatic Spray Deposition -- Effect of the Addition of Nanoporous Carbon Black on the Cycling Characteristics of Li2Co2(MoO4)3 for Lithium Batteries -- Protonic Conduction in TiP2O7 -- Preparation and Electrochemical Characteristics of LiMn2O4 Thin Film by a Solution Deposition Method -- Synthesis and Characterization of LiMPO4 (M = Ni, Co).
Synthesis and Electrical Characterization of LiFeO2, LiCoO2 and NiO Compositions -- Natural Sri Lanka Graphite as Conducting Enhancer in Manganese Dioxide (Emd Type) Cathode of Alkaline Batteries -- Electrochemical Properties of LiNi1-(x+y)AlxZnyO2 Cathode Material Synthesized by Emulsion Method -- LiNi0.80Co0.20O2 Cathode Materials Synthesized by Particulate Sol-gel Method for Lithium Ion Batteries -- Pulsed Laser Deposition of Highly Oriented LiCoO2 and LiMn2O4 Thin Films for Microbattery Applications -- Preparation of LiNi0.80Co0.20O2 Thin Films by Sol-Gel Method -- Electrochemical Lithium Insertion into a Manganese Dioxide Electrode in Aqueous Solutions -- AC Impedance Spectroscopic Analysis of Thin Film LiNiVO4 Prepared by Pulsed Laser Deposition Technique -- Synthesis and Characterization of LiFePO4 Cathode Materials by Microwave Processing -- Characterization of Nd0.8Sr0.2CoO3-δ Including Pt Second Phase as the Cathode Material for Low-Temperature for SOFCs -- Thermodynamic Behavior of Lithium Intercalation into Natural Vein and Synthetic Graphite -- Part III: Electroactive Polymers -- Invited Papers -- Organised or Disorganised? Looking at Polymer Electrolytes from Both Points of View -- Polymer Electrolytes - Simple Low Permittivity Solutions? -- Dependence of Conductivity Enhancement on the Dielectric Constant of the Dispersoid in Polymer-Ferroelectric Composite Electrolytes -- Design and Application of Boron Compounds for High-Performance Polymer Electrolytes -- Structural, Vibrational and AC Impedance Analysis of Nano Composite Polymer Electrolytes based on PVAc -- Absorption Intensity Variation with Ion Association in PEO Based Electrolytes -- Study of Ion-polymer Interactions in Cationic and Anionic lonomers from the Dependence of Conductivity on Pressure and Temperature.
Triol Based Polyurethane Gel Electrolytes for Electrochemical Devices -- Contributed Papers -- Accurate Conductivity Measurements to Solvation Energies in Nafion® -- Ion Conducting Behaviour of Composite Polymer Gel Electrolyte:PEG - PVA - (NH4CH2CO2)2 System -- Impedance Spectroscopy and DSC Studies of Poly(vinyl alcohol)/Silicotungstic Acid Crosslinked Composite Membranes -- (PEO)n:Na4P2O7- A Report on Complex Formation -- Experimental Studies on (PVC+LiClO4+DMP) Polymer Electrolyte Systems for Lithium Battery -- Stability of the Gel Electrolyte, PAN : EC : PC : LiCF3SO3 Towards Lithium -- Montmorillonite as a Conductivity Enhancer in (PEO)9LiCF3SO3 Polymer Electrolyte -- Polymeric Gel Electrolytes for Electrochemical Capacitors -- Electrical Conductivity Studies on Proton Conducting Polymer Electrolytes Based on Poly (vinyl acetate) -- Conductivity and Thermal Studies on Plasticized Nano-Composite Polymer Electrolyte, PEO: EC: LiTf: Al2O3 -- Investigation of Transport Properties of a New Biomaterials - Gum Mangosteen -- Investigation of Ionic Conductivity of PEO- MgCl2 Based Solid Polymer Electrolyte -- 1H NMR and Raman Analysis of Proton Conducting Polymer Electrolytes based on Partially Hydrolyzed Poly (vinyl alcohol) -- Influence of Al2O3 Nanoparticles on the Phase Matrix of Polyethylene Oxide - Silver Triflate Polymer Electrolytes -- Effect of Different Types of Ceramic Nano - Fillers on Thermal Dielectric and Transport Properties of PEO9 LiTf Solid Polymer Electrolyte -- Characterization of PVP Based Solid Polymer Electrolytes Using Spectroscopic Techniques -- Electrochemical and Structural Properties of Polyvinylidene Fluoride - Silver Triflate Solid Polymer Electrolyte System -- Micro Raman 7Li NMR and ac Impedance Analysis of PVAC:LiClO4 Solid Polymer Electrolytes -- Study of Na+ Ion Conduction in PVA-NaSCN Solid Polymer Electrolytes.
Effect of Filler Addition on Plasticized Polymer Electrolyte Systems -- Ionic Motion in PEDOT and PPy Conducting Polymer Bilayers -- Film Formation Mechanism and Electrochemical Characterization of V2O5 Xerogel Intercalated by Polyaniline -- Effect of NH4NO3 Concentration on the Conductivity of PVA Based Solid Polymer Electrolyte -- Dielectric and Conductivity Studies of PVA-KSCN based Solid Polymer Electrolytes -- Part IV: Emerging Applications -- Invited Papers -- The Use of Solid States Ionic Materials and Devices in Medical Applications -- Development of All-Solid-State Lithium Batteries -- Reversible Intermediate Temperature Solid Oxide Fuel Cells -- Nano-Size Effects in Lithium Batteries -- Electrochromics: Fundamentals and Applications -- Electrochemical CO2 Gas Sensors -- Polypyrrole for Artificial Muscles: Ionic Mechanisms -- Development and Characterization of Polyfluorene based Light Emitting Diodes and their Colour Tuning using Forester Resonance Energy Transfer -- Mesoporous and Nanoparticulate Metal Oxides: Applications in New Photocatalysis -- Proton Conducting (PC) Perovskite Membranes for Hydrogen Separation and PC-SOFC Electrodes and Electrolytes -- Contributed Papers -- Electroceramic Materials for the Development of Natural Gas Fuelled SOFC/GT Plant in Developing Country (Trinidad and Tobago (T&T)) -- Thin Film SOFC Supported on Nano-Porous Substrate -- Characterization and Fabrication of Silver Solid State Battery Ag/AgI-AgPO3/I2,C -- Performance of Lithium Polymer Cells with Polyacrylonitrile based Electrolyte -- Hydrothermal Synthesis and Electrochemical Behavior of MoO3 Nanobelts for Lithium Batteries -- Electrochemical Behaviour of a PPy (DBS)/Polyacrylonitrile :LiTF:EC:PC/Li Cell -- Characteristics of Thick Film CO2 Sensors Based on NASICON using Li2CO3-CaCO3 Auxiliary Phases.
Solid State Battery Discharge Characteristic Study on Fast Silver Ion Conducting Composite System: 0.9[0.75AgI:0.25AgCl]: 0.1TiO2.
Summary: The field of solid state ionics deals with ionically conducting materials in the solid state and numerous devices based on such materials. Solid state ionic materials cover a wide spectrum, ranging from inorganic crystalline and polycrystalline solids, ceramics, glasses, polymers, composites and nano-scale materials. A large number of Scientists in Asia are engaged in research in solid state ionic materials and devices and since 1988. The Asian Society for solid state ionics has played a key role in organizing a series of bi-ennial conferences on solid state ionics in different Asian countries. The contributions in this volume were presented at the 10th conference in the series organized by the Postgraduate Institute of Science (PGIS) and the Faculty of Science, University of Peradeniya, Sri Lanka, which coincided with the 10th Anniversary of the Postgraduate Institute of Science (PGIS). The topics cover solid state ionic materials as well as such devices as solid state batteries, fuel cells, sensors, and electrochromic devices. The aspects covered include theoretical studies and modeling, experimental techniques, materials synthesis and characterization, device fabrication and characterization. Sample Chapter(s). Chapter 1: Challenges and Opportunities of Solid State Ionic Devices (607 KB). Contents: Ionically Conducting Inorganic Solids; Electrode Materials; Electroactive Polymers; Emerging Applications. Readership: Researchers in physics, chemistry and materials science.
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Intro -- Contents -- Preface -- Keynote Lecture -- Challenges and Opportunities of Solid State Ionic Devices -- Part I: Ionically Conducting Inorganic Solids -- Invited Papers -- Multinuclear NMR Studies of Mass Transport of Phosphoric Acid in Water -- Crystalline, Glassy and Polymeric Electrolytes: Similarities and Differences in Ionic Transport Mechanisms -- 30 Years of NMR/NQR Experiments in Solid Electrolytes -- Analysis of Conductivity and NMR Measurements in Li3xLa2/3-xTiO3 Fast Li+ Ionic Conductor: Evidence for Correlated Li+ Motion -- Transport Pathways for Ions in Disordered Solids from Bond Valence Mismatch Landscapes -- The Proton Conductivity in Condensed Phases of Water: Implications on Linear and Ball Lightning -- Contributed Papers -- Proton Transport in Nanocrystalline Bioceramic Materials: An Investigative Study of Synthetic Bone with that of Natural Bone -- Synthesis and Properties of the Nanostructured Fast Ionic Conductor Li0.3La0.56TiO3 -- Hydrogen Production: Ceramic Materials for High Temperature Water Electrolysis -- Influence of the Sintering Temperature on pH Sensor Ability of Li3xLa2/3-xTiO3. Relationship between Potentiometric and Impedance Spectroscopy Measurements -- Microstructure Chracterization and Ionic Conductivity of Nano-Sized CeO2-Sm2O3 (x = 0.05 - 0.2) System Prepared by Combustion Route -- Red Soil in Northern Sri Lanka is a Natural Magnetic Ceramic -- Neutron Scattering of LiNiO2 -- Preparation and Properties of LiFePO4 Nanorods -- Structural and Electrochemical Properties of Monoclinic and Othorhombic MoO3 Phases -- Preparation of Zircon (ZrSiO4) Ceramics via Solid State Sintering of ZrO2 and SiO2 and the Effect of Dopants on the Zircon Yield -- Preparation and Properties of Vanadium Doped ZnTe Cermet Thin Films -- Dynamical Properties and Electronic Structure of Lithium-ion Conductor.

Cuprous Ion Conducting Montmorillonite- Polypyrrole Nanocomposites -- Frequency Dependence of Conductivity Studies on a Newly Synthesized Superionic Solid Solution/Mixed System: [0.75AgI: 0.25AgCl] -- Diffuse X-ray and Neutron Scattering from Powder PbS -- Electron Affinity and Work Function of Pyrolytic MnO2 Thin Films Prepared from Mn(C2H3O2)2.4H2O -- Crystal Structure and Heat Capacity of Ba3Ca1.18Nb1.82O8.73 -- XPS and Impedance Investigations on Amorphous Vanadium Oxide Thin Films -- Sintering and Mixed Electronic-Ionic Conducting Properties of La1.9Sr0.1NiO4+8 Derived from a Polyaminocarboxylate Complex Precursor -- Preparation and Characteristics of Ball Milled MgH2 + M (M = Fe, FeF3 and VF3) Nanocomposites for Hydrogen Storage -- Structural Studies of Oxysulfide Glasses by X-Ray Diffraction and Molecular Dynamics Simulation -- Synthesis, Sintering and Oxygen Ionic Conducting Properties of Bi2V0.9Cu0.1O5.5-δ -- Synthesis and Transport Characteristics of PbI2-Ag2O-Cr2O3 Superionic System -- Electronic Conductivity of La0.8Sr0.2Ga0.8Mg0.2-xCoxO3-δ Electrolytes (II) -- Part II: Electrode Materials -- Invited Papers -- Cathodic Properties of Al-Doped LiCoO2 Prepared by Molten Salt Method for Li-Ion Batteries -- Layered Ion-Electron Conducting Materials -- LiNi0.80Co0.20O2 Cathode Thin-film Prepared by RF Sputtering for All-Solid-State Rechargeable Microbatteries -- Contributed Papers -- Nanocomposite Cathode for SOFCs Prepared by Electrostatic Spray Deposition -- Effect of the Addition of Nanoporous Carbon Black on the Cycling Characteristics of Li2Co2(MoO4)3 for Lithium Batteries -- Protonic Conduction in TiP2O7 -- Preparation and Electrochemical Characteristics of LiMn2O4 Thin Film by a Solution Deposition Method -- Synthesis and Characterization of LiMPO4 (M = Ni, Co).

Synthesis and Electrical Characterization of LiFeO2, LiCoO2 and NiO Compositions -- Natural Sri Lanka Graphite as Conducting Enhancer in Manganese Dioxide (Emd Type) Cathode of Alkaline Batteries -- Electrochemical Properties of LiNi1-(x+y)AlxZnyO2 Cathode Material Synthesized by Emulsion Method -- LiNi0.80Co0.20O2 Cathode Materials Synthesized by Particulate Sol-gel Method for Lithium Ion Batteries -- Pulsed Laser Deposition of Highly Oriented LiCoO2 and LiMn2O4 Thin Films for Microbattery Applications -- Preparation of LiNi0.80Co0.20O2 Thin Films by Sol-Gel Method -- Electrochemical Lithium Insertion into a Manganese Dioxide Electrode in Aqueous Solutions -- AC Impedance Spectroscopic Analysis of Thin Film LiNiVO4 Prepared by Pulsed Laser Deposition Technique -- Synthesis and Characterization of LiFePO4 Cathode Materials by Microwave Processing -- Characterization of Nd0.8Sr0.2CoO3-δ Including Pt Second Phase as the Cathode Material for Low-Temperature for SOFCs -- Thermodynamic Behavior of Lithium Intercalation into Natural Vein and Synthetic Graphite -- Part III: Electroactive Polymers -- Invited Papers -- Organised or Disorganised? Looking at Polymer Electrolytes from Both Points of View -- Polymer Electrolytes - Simple Low Permittivity Solutions? -- Dependence of Conductivity Enhancement on the Dielectric Constant of the Dispersoid in Polymer-Ferroelectric Composite Electrolytes -- Design and Application of Boron Compounds for High-Performance Polymer Electrolytes -- Structural, Vibrational and AC Impedance Analysis of Nano Composite Polymer Electrolytes based on PVAc -- Absorption Intensity Variation with Ion Association in PEO Based Electrolytes -- Study of Ion-polymer Interactions in Cationic and Anionic lonomers from the Dependence of Conductivity on Pressure and Temperature.

Triol Based Polyurethane Gel Electrolytes for Electrochemical Devices -- Contributed Papers -- Accurate Conductivity Measurements to Solvation Energies in Nafion® -- Ion Conducting Behaviour of Composite Polymer Gel Electrolyte:PEG - PVA - (NH4CH2CO2)2 System -- Impedance Spectroscopy and DSC Studies of Poly(vinyl alcohol)/Silicotungstic Acid Crosslinked Composite Membranes -- (PEO)n:Na4P2O7- A Report on Complex Formation -- Experimental Studies on (PVC+LiClO4+DMP) Polymer Electrolyte Systems for Lithium Battery -- Stability of the Gel Electrolyte, PAN : EC : PC : LiCF3SO3 Towards Lithium -- Montmorillonite as a Conductivity Enhancer in (PEO)9LiCF3SO3 Polymer Electrolyte -- Polymeric Gel Electrolytes for Electrochemical Capacitors -- Electrical Conductivity Studies on Proton Conducting Polymer Electrolytes Based on Poly (vinyl acetate) -- Conductivity and Thermal Studies on Plasticized Nano-Composite Polymer Electrolyte, PEO: EC: LiTf: Al2O3 -- Investigation of Transport Properties of a New Biomaterials - Gum Mangosteen -- Investigation of Ionic Conductivity of PEO- MgCl2 Based Solid Polymer Electrolyte -- 1H NMR and Raman Analysis of Proton Conducting Polymer Electrolytes based on Partially Hydrolyzed Poly (vinyl alcohol) -- Influence of Al2O3 Nanoparticles on the Phase Matrix of Polyethylene Oxide - Silver Triflate Polymer Electrolytes -- Effect of Different Types of Ceramic Nano - Fillers on Thermal Dielectric and Transport Properties of PEO9 LiTf Solid Polymer Electrolyte -- Characterization of PVP Based Solid Polymer Electrolytes Using Spectroscopic Techniques -- Electrochemical and Structural Properties of Polyvinylidene Fluoride - Silver Triflate Solid Polymer Electrolyte System -- Micro Raman 7Li NMR and ac Impedance Analysis of PVAC:LiClO4 Solid Polymer Electrolytes -- Study of Na+ Ion Conduction in PVA-NaSCN Solid Polymer Electrolytes.

Effect of Filler Addition on Plasticized Polymer Electrolyte Systems -- Ionic Motion in PEDOT and PPy Conducting Polymer Bilayers -- Film Formation Mechanism and Electrochemical Characterization of V2O5 Xerogel Intercalated by Polyaniline -- Effect of NH4NO3 Concentration on the Conductivity of PVA Based Solid Polymer Electrolyte -- Dielectric and Conductivity Studies of PVA-KSCN based Solid Polymer Electrolytes -- Part IV: Emerging Applications -- Invited Papers -- The Use of Solid States Ionic Materials and Devices in Medical Applications -- Development of All-Solid-State Lithium Batteries -- Reversible Intermediate Temperature Solid Oxide Fuel Cells -- Nano-Size Effects in Lithium Batteries -- Electrochromics: Fundamentals and Applications -- Electrochemical CO2 Gas Sensors -- Polypyrrole for Artificial Muscles: Ionic Mechanisms -- Development and Characterization of Polyfluorene based Light Emitting Diodes and their Colour Tuning using Forester Resonance Energy Transfer -- Mesoporous and Nanoparticulate Metal Oxides: Applications in New Photocatalysis -- Proton Conducting (PC) Perovskite Membranes for Hydrogen Separation and PC-SOFC Electrodes and Electrolytes -- Contributed Papers -- Electroceramic Materials for the Development of Natural Gas Fuelled SOFC/GT Plant in Developing Country (Trinidad and Tobago (T&T)) -- Thin Film SOFC Supported on Nano-Porous Substrate -- Characterization and Fabrication of Silver Solid State Battery Ag/AgI-AgPO3/I2,C -- Performance of Lithium Polymer Cells with Polyacrylonitrile based Electrolyte -- Hydrothermal Synthesis and Electrochemical Behavior of MoO3 Nanobelts for Lithium Batteries -- Electrochemical Behaviour of a PPy (DBS)/Polyacrylonitrile :LiTF:EC:PC/Li Cell -- Characteristics of Thick Film CO2 Sensors Based on NASICON using Li2CO3-CaCO3 Auxiliary Phases.

Solid State Battery Discharge Characteristic Study on Fast Silver Ion Conducting Composite System: 0.9[0.75AgI:0.25AgCl]: 0.1TiO2.

The field of solid state ionics deals with ionically conducting materials in the solid state and numerous devices based on such materials. Solid state ionic materials cover a wide spectrum, ranging from inorganic crystalline and polycrystalline solids, ceramics, glasses, polymers, composites and nano-scale materials. A large number of Scientists in Asia are engaged in research in solid state ionic materials and devices and since 1988. The Asian Society for solid state ionics has played a key role in organizing a series of bi-ennial conferences on solid state ionics in different Asian countries. The contributions in this volume were presented at the 10th conference in the series organized by the Postgraduate Institute of Science (PGIS) and the Faculty of Science, University of Peradeniya, Sri Lanka, which coincided with the 10th Anniversary of the Postgraduate Institute of Science (PGIS). The topics cover solid state ionic materials as well as such devices as solid state batteries, fuel cells, sensors, and electrochromic devices. The aspects covered include theoretical studies and modeling, experimental techniques, materials synthesis and characterization, device fabrication and characterization. Sample Chapter(s). Chapter 1: Challenges and Opportunities of Solid State Ionic Devices (607 KB). Contents: Ionically Conducting Inorganic Solids; Electrode Materials; Electroactive Polymers; Emerging Applications. Readership: Researchers in physics, chemistry and materials science.

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